Product ID:AGK 100 BOILER & FEEDWATER TREATMENT
MSDS Date:11/20/1996
FSC:6850
NIIN:01-064-0275
MSDS Number: CCLWL

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

3849 FISHER RD
COLUMBUS, OH 43228
US

Emergency Phone: 800-274-5263

Info Phone: 614-889-3333

Cage: 7L600

DREW CHEMICAL CORP,DIV OF ASHLAND CHEMICAL CO

BOONTON, NJ 07005 US

Telephone: 606-324-1133

Cage: 52454

MORPHOLINE(INFORMATION PROVIDED BY ADOLPHO

CAS: 110-91-8

RTECS: QD6475000

Fraction By Weight: 10.4%

OSHA PEL S, 20 PPM

ACGIH TLV: S, 20 PPM; 9596

HYDRAZINE (SARA 302/313) (CERCLA)

CAS: 302-01-2

RTECS: MU7175000

Fraction By Weight: 6.3%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 0.01 PPM, A3;9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

POTASSIUM HYDROXIDE (CERCLA)(INFORMATION PROVIDED BY

CAS: 1310-58-3

RTECS: TT2100000

Fraction By Weight: 2.7%

OSHA PEL C 2 MG/M3

ACGIH TLV: C 2 MG/M3; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TETRAPOTASSIUM PYROPHOSPHATE(INFORMATION PROVIDED BY

CAS: 7320-34-5

RTECS: JL6735000

Fraction By Weight: 1.44%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:**CORROSIVE,TOXIC** EYES:IRREVERSIBLE
DAMAGE.SKIN:IRREVERSIBLE DAMAGE AND ALLERGIC REACTIONS.HYDRAZINE IS
DERMALLY ABSORBED WITH CUMULATIVE OR DELAYED EFFECTS.INGEST:HARMFUL
OR FATAL.INHAL:HARMFUL OR FATAL.CAUSES BURNS.CHRONIC:HYDRAZINE
MAYDAMAGE KIDNEY,LIVER,BLOOD FORMING ORGANS & CAUSE CNS DEPRESSION.
Explanation of
Carcinogenicity:HYDRAZINE:NTP-AC,IARC-2B,EPA-B2,ACGIH-A2.
Effects of Overexposure:EYES:STINGING,TEARING,REDNESS,SWELLING,CORNEAL
DAMAGE,BLINDNESS.SKIN:REDNESS,SWELLING,BURNS.(HYDRAZINE:DIZZINESS,N
AUSEA)INGEST:NAUSEA,VOMITING,DIARRHEA,ABDOMINAL PAIN,VOMITING OF
BLOOD,LOW BLOOD PRESS URE AND SHOCK.INHAL:HEADACHE,MUSCLE
WEAKNESS,LUNG DAMAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
LIVER,EYE,KIDNEY AND RESPIRATORY AILMENTS MAY BE AT INCREASED RISK
FROM EXPOSURE.

First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.IF SKIN
DAMAGE OCCURS,GET IMMEDIATE MEDICAL ATTENTION.EYES:FLUSH WITH WATER
FOR 15 MINUTES.GET IMMEDIATE MEDICAL ATTENTION.INHAL:REMOVE TO
FRESH AIR.G ET IMMEDIATE MEDICAL ATTENTION.KEEP WARMAND QUIET.GIVE
OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE
VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.

Flash Point:NONE
Lower Limits:1.8
Upper Limits:10.8
Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE,REGULAR FOAM.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:DECOMPOSITION PRODUCTS MAY BE
TOXIC.VAPORS ARE HEAVIER THAN AIR,CAN TRAVEL DISTANCES ALONG THE
GROUND,AND FLASHBACK AT THE SOURCE.

Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE
EQUIPMENT.VENTILATE AREA.SOAK UP WITH A NON-COMBUSTIBLE INERT
ABSORBANT(CLAY,SAND);PLACE SMALL AMOUNTS UNDER A FUME HOOD;PLACE
LARGE AMOUNTS IN PROPER CONTAINER F OR DISPOSAL.AVOID CONTAMINATION
OF GRND&WATERWAYS.
Neutralizing Agent:NOT REPORTED.

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM
HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS
RESIDUE;DISPOSE OF PROPERLY.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS.IN LESS
HAZARDOUS CONDITIONS,A NIOSH/MSHA RESPIRATOR FOR CORROSIVE MISTS
MAY BE USED.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves:NEOPRENE,NITRILE.
Eye Protection:CHEMICAL SPLASH GOGGLES+FACESHIELD(8").
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
DO NOT MIX WITH SODIUM NITRITE,OR ANY OTHER NITRSATING AGENT;CANCER
CAUSING NITROSAMINES MAY BE FORMED.HYDRAZINE IS A STRONG IRRITANT,A
SKIN SENSITIZER,A CONVULSANT,IS TOXIC TO THE LIVER AND DESTROYS
RED BLOOD CELLS.

HCC:B1
Boiling Pt:=100.C, 212.F
Vapor Pres:17.5
Vapor Density:>1
Spec Gravity:1.04
pH:13.9
Evaporation Rate & Reference:>1 ETHER=1
Appearance and Odor:SLIGHTLY HAZY TO DARK AMBER LIQUID(HOMOGENEOUS
SOLUTION)
Corrosion Rate:CORROSIV

Stability Indicator/Materials to Avoid:YES
CYANIDES,STRONG ORGANIC ACIDS,STRONG OXIDIZING AGENTS.SEE SUPPLIMENTAL.
Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON
MONOXIDE,AMMONIA,NITROGEN COMPOUNDS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.